Biosorption of Pb(II) and Cr(III) from aqueous solutions: breakthrough curves and modeling studies

The sorption capacity parameters obtained for batch studies provide useful information about biosorption system. However, such data fail to explain the process under continuous-flow conditions. The present study is an attempt to explore the biosorption of Pb(II) and Cr(III) by straw from local wheat (Triticum aestivum). The biosorbent has been characterized by using Fourier transform infrared spectroscopy and surface area and elemental analyses and found to be porous and polyfunctional. S-shaped breakthrough curves were obtained at different column heights for the both metal ions. Various breakthrough parameters and saturation times have been determined. The column data have been successfully used to study the Bohart–Adams' bed depth service time (BDST) model and Yoon and Nelson's model. It was found that BDST model quite efficiently explained the whole column data whereas Yoon and Nelson model could explain it below 90 % breakthrough concentration. The predicted and calculated BDST parameters were in agreement with each other. Yoon and Nelson's constant decreased with an increase in the column height for both metal ions. Effect of change in flow rate on the Pb(II) biosorption has also been discussed with respect to BDST approach.     

Water pollution in Pakistan and its impact on public health--a review

Water pollution is one of the major threats to public health in Pakistan. Drinking water quality is poorly managed and monitored. Pakistan ranks at number 80 among 122 nations regarding drinking water quality. Drinking water sources, both surface and groundwater are contaminated with coliforms, toxic metals and pesticides throughout the country. Various drinking water quality parameters set by WHO are frequently violated. Human activities like improper disposal of municipal and industrial effluents and indiscriminate applications of agrochemicals in agriculture are the main factors contributing to the deterioration of water quality. Microbial and chemical pollutants are the main factors responsible exclusively or in combination for various public health problems. This review discusses a detailed layout of drinking water quality in Pakistan with special emphasis on major pollutants, sources of pollution and the consequent health problems. The data presented in this review are extracted from various studies published in national and international journals. Also reports released by the government and non-governmental organizations are included.     

Effect of Cell-to-matrix Ratio in Polyvinyl Alcohol Immobilized Pure and Mixed Cultures on Atrazine Degradation

Atrazine biodegradation by immobilized pure and mixed cultures was examined. A pure atrazine-degrading culture, Agrobacterium radiobacter J14a (J14a), and a mixed culture (MC), isolated from an atrazine-contaminated crop field, were immobilized using phosphorylated-polyvinyl alcohol (PPVA). An existing cell immobilization procedure was modified to enhance PPVA matrix stability. The results showed that the matrices remained mechanically and chemically stable after shaking with glass beads over 15 days under various salt solutions and pH values. The immobilization process had a slight effect on cell viability. With the aid of scanning electron microscopy, a suitable microstructure of PPVA matrices for cell entrapment was observed. There were two porous layers of spherical gel matrices, the outside having an encapsulation property and the inside containing numerous pores for bacteria to occupy. J14a and MC were immobilized at three cell-to-matrix ratios of 3.5, 6.7, and 20 mg dry cells/mL matrix. The atrazine biodegradation tests were conducted in an aerobic batch system, which was inoculated with cells at 2,000 mg/L. The tests were also conducted using free (non-immobilized) J14a and MC for comparative purpose. The cell-to-matrix ratio of 3.5 mg/mL provided the highest atrazine removal efficiency of 40–50% in 120 h for both J14a and MC. The free cell systems, for both cultures, presented much lower atrazine removal efficiencies compared to the immobilized cell systems at the same level of inoculation.     

Ozonation catalyzed by homogeneous and heterogeneous catalysts for degradation of DEHP in aqueous phase

Di-(2-ethyl hexyl) phthalate (DEHP), a recalcitrant and an endocrine disrupting chemical, was studied for its removal from wastewater by advanced oxidation process. The effects of pH, transition metal ions, and granular activated carbon (GAC) were investigated. Removal of DEHP increased with increase in pH and among metal ions Cr(III) was found to be the most active catalyst to remove DEHP. In the case of GAC, original carbon (G0) and GAC pre-ozonated in gas phase for 10 min (G10) were tested as catalysts in catalytic ozonation and found G0 to be more active than G10. This is because, during pre-ozonation, basic groups like chromene, pyrones and also graphene layers were oxidized to acidic surface oxygen groups. These basic surface groups are reported to be active catalytic centres for ozone decomposition into .OH which is a strong oxidant. According to kinetic manipulations, DEHP degradation rate constant due to .OH was affected by the catalyst while that due to direct ozonation is same in all cases with or without catalyst. G0 was doped with chromia gels (G0/CrA) to combine the benefits of homogeneous and heterogeneous catalysis. G0/CrA showed lower catalytic efficiency than that of only G0. This might be because of changes in surface structure of GAC caused by doping of chromia gel and changes in chemical nature of Cr(III) during formation of gel. A good correlation was found between the rate constants of ozone decay and DEHP degradation (R2=0.96). This correlation confirms that ozone decomposition into .OH is a critical factor for the activity of a catalyst during ozonation.     

Conservation of biodiversity in western India

Director of environmental studies at the Indira Gandhi Centre for Human Ecology, Environmental and Population Studies at the University of Rajasthan. This paper describes the biodiversity in the north-western Indian State of Rajasthan, its relationship with the environment and the existing human and livestock populations. As the biodiversity is depleting in this area due to zoogenic and anthropogenic reasons, certain pragmatic conservation strategies are advocated. The north-western part of India is occupied by a desert ecosystem, the Thar Desert. Animal husbandry is the major livelihood in the region, followed by agriculture. The vegetation, which is predominantly xerophytic and quite sparse, occurs in great variety. Six hundred and eighty-two plant species and 390 animal species have been identified from the Thar Desert. Many plant and animal species have become endangered due to zoogenic and anthropogenic activities. Plants such as Calligonum polygonoides, Tecomella undulata and Prosopis cineraria urgently require conservation.     

GROUND WATER SIMULATION USING A ONE DIMENSIONAL FLOW MODEL1

ABSTRACT: In projects involving ground water problems, dependence on the mathematical modeling of the ground water flow phenomena is inescapable. At present, two dimensional flow models, which require tremendous amounts of computer time and storage, are generally used. When such bulky models are used for planning purposes, the two requirements (computer time and storage) can severely limit the number of alternatives that can be considered. A simple quantity and quality simulation model is developed here which requires considerably less computer time and storage and gives reasonably accurate results. The model was applied to simulate a ground water basin in San Luis Rey River in Southern California. The results were compared with those obtained by a USGS model. It was found that the simple model gave results which were consistentaly within five percent of the USGS model results, while the requirements on computer time and storage were drastically reduced.     

The international natural rubber agreement 1979

The International Natural Rubber Agreement (INRA) 1979 is the first, and so far the only, commodity agreement to emerge from the negotiations under the Integrated Programme for Commodities (IPC). The agreement is examined in the context of the issues relating to international stock and as an indicator for future development. The author concludes that while the principle of joint responsibility for financing international stock has been for the first time accepted in INRA, this has been achieved at the cost of reducing the scope of the regulatory mechanism, and that the single-instrument pattern that the agreement has adopted may not be suitable or acceptable in other commodities.     

Reproduction in mice treated with crufomate: effects of dermal treatments on female mice and on their progeny.

Dermal treatments with crufomate 100 or 50 mg/kg or crufomate vehicle 100 mg/kg were applied to mice either on days 35 and 21 before mating or on days 70, 56, 35, and 21 before mating. Two, but not four dermal treatments, with both doses of crufomate reduced the mating reponse and conception rate in mice. The mice either did not produce a litter or the litter died before the age of 7 days. Four treatments with crufomate 100 mg/kg, but not with 50 mg/kg, reduced the weaning weight of progeny weaned at the age of 21 days. The vehicle had no effects on reproduction and increased the weights at maturity of female and male progeny of mice given two and four treatments, respectively.     

Bioavailability to rats of bound [14C] pirimiphos-methyl in stored wheat.

Stored wheat treated with radiolabelled pirimiphos-methyl (0-2-diethyl-amino-6-methyl-pyrimidin-4-yl 0,0-dimethyl phosphorothioate) formed bound (nonextractable) 14C residues. Supercritical fluid extraction, gas chromatography and mass spectrometric techniques were used to identify and quantitate the 14C bound residues in wheat grains. The amount of bound 14C residues present after 28 weeks of storage was about 9.9% of the applied radioactivity. Pirimiphos-methyl accounted for 80% of the bound residue. Grain-bound residues were fed to rats for 5 days. After a total period of 8 days a substantially large percentage of the administered bound 14C residues (72.9%) was eliminated in urine while feces contained only 17.9%. Bound pirimiphos-methyl in wheat grain was metabolized in rats by processes involving hydrolysis, N-dealkylation and 0-demethylation. The results indicate that wheat-bound residues of pirimiphos-methyl are highly bioavailable to the rat and may possess a toxicological potential as manifested by a significant reduction in body weight gain.     

Limitation of communal latrines in changing the prevalence of parasites and diarrhoeal attack rate in Dhaka Peri-urban slums

A study of the effects of communal latrines on diarrhoeal incidence and parasite prevalence rates was conducted in 1983 at Tongi, which had five communal Oxfam latrines with a manual flushing system for 924 people; and at Kalsi, which had 39 open fit latrines for 823 people. Inhabitants' stool samples were tested initially and also after twelve months to see the reinfection rates. All inhabitants were dewormed with pyrantel, and were visited weekly to obtain diarrhoea histories. In both communities, there were high prevalence rates of roundworm, hookworm, Trichuris trichiura, Entamoeba histolytica, Giardia lambia and Strongyloides stercoralis. Following the dewormings, the prevalence rates of roundworm, hookworm and Trichuris infection came down significantly, in both areas. The prevalence or reinfection rates remained identical in both communities. There was also no difference in diarrhoea incidence rate for the two areas. It is found that keeping all other variables unchanged, use of communal latrines, without strict disposal of everyone's excreta, does not affect parasite prevalence and diarrhoea rates. People must be educated about the use of communal latrines and the safe disposal of all excreta, including that of children.